A cause for the strange behaviour of cuprates discovered: a step towards more sustainable superconductor applications

The study by Politecnico di Milano, Chalmers University of Technology, and Sapienza University of Rome, published in Nature Communications

A significant step forward in superconductivity research, the discovery could pave the way for sustainable technologies and contribute to a more environmentally friendly future.

The study just published in Nature Communications by researchers from Politecnico di Milano, Chalmers University of Technology in Göteborg and Sapienza University of Rome sheds light on one of the many mysteries of high-critical-temperature copper-based superconductors: even at temperatures above the critical temperature, they are special, behaving like "strange" metals. This means that their electrical resistance changes with temperature differently than that of normal metals.

The research hints at the existence of a quantum critical point connected to the phase called "strange metal". "A quantum critical point identifies specific conditions where a material undergoes a sudden change in its properties due solely to quantum effects. Just like ice melts and becomes liquid at zero degrees Celsius due to microscopic temperature effects, cuprates turn into a "strange" metal because of quantum charge fluctuations" says Riccardo Arpaia, a researcher at the Department of Microtechnology and Nanoscience at Chalmers and leading author of the study.

The research is based on X-ray scattering experiments conducted at the European Synchrotron ESRF and the British synchrotron Diamond Light Source. They reveal the existence of charge density fluctuations affecting the electrical resistance of cuprates in such a way as to make them "strang". The systematic measurement of how the energy of these fluctuations varies allowed identifying the value of the charge carrier density at which this energy is minimum: the quantum critical point.

"This is the result of more than five years of work. We used a technique, called RIXS, largely developed by us at the Politecnico di Milano. Thanks to numerous measurement campaigns and new data analysis methods, we were able to prove the existence of the quantum critical point. A better understanding of cuprates will guide the design of even better materials, with higher critical temperatures, and therefore easier to exploit in tomorrow's technologies" says Giacomo Ghiringhelli, Professor at the Physics Department of the Politecnico di Milano and coordinator of the research.

"This discovery represents an important advancement in understanding not only the anomalous properties of the metallic state of cuprates but also the still obscure mechanisms underlying high-temperature superconductivity" says Sergio Caprara, Professor at the Physics Department of Sapienza University of Rome, who developed the theory that assigns charge fluctuations a key role in cuprates together with colleagues in the Rome theoretical group. 



Signature of quantum criticality in cuprates by charge density fluctuations - Riccardo Arpaia, Leonardo Martinelli, Marco Moretti Sala, Sergio Caprara, Abhishek Nag, Nicholas B. Brookes, Pietro Camisa, Qizhi Li, Qiang Gao, Xingjiang Zhou, Mirian Garcia-Fernandez, Ke-Jin Zhou, Enrico Schierle, Thilo Bauch, Ying Ying Peng, Carlo Di Castro, Marco Grilli, Floriana Lombardi, Lucio Braicovich & Giacomo Ghiringhelli - Nature Communications (2023). https://doi.org/10.1038/s41467-023-42961-5


Further Information 

Sergio Caprara
Department of Physics



Monday, 11 December 2023

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